Fans of organic chemistry, in theory at least | Student-run twitter. We have moved to Bluesky: @tantillogroup.bsky.social
Davis, CA
Joined January 2021
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Tantillo Lab retweeted
Post-transition State Bifurcations in Reactions That Form Pimarenyl Cation Diastereomers─Implications for Terpene Biosynthesis | Journal of the American Chemical Society @ucdavis @TantilloLab
@UCDChem pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Professor Dean Tantillo @TantilloLab has received the 2025 ACS Edward Leete Award! This national award from the Division of Organic Chemistry honors outstanding contributions to teaching and research in Organic Chemistry. Congratulations!
organicdivision.org/blog/new…
Tantillo Lab retweeted
Avoidance of Secondary Carbocations, Unusual Deprotonation, and Nonstatistical Dynamic Effects in the Cyclization Mechanism of Tetraisoquinane | Journal of the American Chemical Society @ucdavis @UCDavisResearch @TantilloLab @UF pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Characterization and Engineering of a Bisabolene Synthase Reveal an Unusual Hydride Shift and Key Residues Critical for Mono-, Bi-, and Tricyclic Sesquiterpenes Formation | Journal of the American Chemical Society @TantilloLab
@UCDChem @PKU1898 pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Vibrationally Assisted Tunneling through the Bread of a Proton Sandwich─Connections to Dynamic Matching | Journal of the American Chemical Society @ucdavis @UCDChem @gabepgomes @CarnegieMellon
@gpggrp pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Post-Transition State Bifurcation Leading to Diradical & Zwitterionic Intermediates: Controlling Nonstatistical Kinetic Selectivity via Solvent Effects | Journal of the American Chemical Society @UWMadisonChem @UWMadison @UCDChem
@ucdavis pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Biomimetic Synthesis of Azorellolide via Cyclopropylcarbinyl Cation Chemistry | Journal of the American Chemical Society @Penn @DirkTrauner @TantilloLab @UCDChem #Biomimetic #Azorellolide #Cyclopropylcarbinyl #Cation @TotalSynthesis @TotalSyntheses pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Azorellolide! How can you not work on a natural product that starts with "Azo"? Great collaboration with @TantilloLab.
I have to say my respect for carbocations has enormously gown through this project. They are just too high in energy and have too many options. But you can tame them!
pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
A curious case of truncated [1.1.1]propellane oligomerization demonstrates that selective one-pot [2]staffane formation becomes possible with either SF5Cl or CF3SF4Cl through radical polarity matching. Thanks to Beilstein JOC for the invited manuscript! beilstein-journals.org/bjoc/…
Tantillo Lab retweeted
nuclear quantum effects, proton sandwiches, ML-accelerated ab initio molecular dynamics, and a lot of physical organic chemistry! @TantilloLab 🤝 @gpggrp, work done by the incredible Yusef Ahmed. preprint: chemrxiv.org/engage/chemrxiv…
Tantillo Lab retweeted
Please check out our crinipellin synthesis @J_A_C_S ! Special thanks to @TantilloLab for the DFT calculations!
Concise Total Syntheses of (−)-Crinipellins A and B Enabled by a Controlled Cargill Rearrangement | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Check out our recent work on "Cobalt-Catalyzed Deacylative Ipso-C–C Bond Functionalization" out in @JOC_OL @ACSPublications
Congratulations👏@ShyamBanjare7 @afreen_sai27358
@NandaTanmayee
@Gopalkr51278158 @TantilloLab and all the authors.
doi.org/10.1021/acs.joc.3c01…
Tantillo Lab retweeted
Concise #TotalSyntheses of (−)-Crinipellins A and B Enabled by a Controlled Cargill Rearrangement by Bo Xu, Ziyao Zhang, Dean J. Tantillo @TantilloLab at @UCDChem, and @MingjiDai at @EmoryChem in @J_A_C_S pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
Overcoming a Radical Polarity Mismatch in Strain-Release Pentafluorosulfanylation of [1.1.0]Bicyclobutanes: An Entryway to Sulfone- and Carbonyl-Containing SF5-Cyclobutanes (Cody Ross Pitts and co-workers) @CRP_Laboratory @TantilloLab onlinelibrary.wiley.com/doi/…
Tantillo Lab retweeted
DiRhodium -Catalyzed Combined CH(C)-Functionalization/Cope Rearrangements: Does Post-Transition-State Dynamic Mismatching Influence Product Distributions? @UCDChem @ucdavis @TantilloLab #Rh #CHFunctionalization #Product #Distribution @TotalSyntheses pubs.acs.org/doi/10.1021/jac…
Tantillo Lab retweeted
This paper by @ClaireMagnani, @TantilloLab, @Joserhern1 and Thomas J. Maimone explores pyridine dearomatization as a tactic in both the total synthesis and biosynthesis of altemicidin.
Check it out 👉 go.acs.org/7LZ
@UCB_Chemistry
Tantillo Lab retweeted
The manuscript introduces seven (yes, seven) independently optimized methodologies, provides the first structural insight on SF5–cyclobutanes, and explores mechanistic features (accounting for byproduct formation) experimentally and computationally with @TantilloLab.
Tantillo Lab retweeted
In a study appearing in @Nature, @UCDChem researchers from the @TantilloLab step closer to mimicking nature’s mastery of #chemistry by harnessing aliphatic hydrocarbons: lettersandscience.ucdavis.ed…
Tantillo Lab retweeted
Unified Synthesis of 2-Isocyanoallopupukeanane and 9-Isocyanopupukeanane through a "Contra-biosynthetic" Rearrangement (Richmond Sarpong and co-workers) @SarpongGroup @TantilloLab #openaccess onlinelibrary.wiley.com/doi/…
Tantillo Lab retweeted
Congratulations to Melissa, Jack, Kenta, Isabel, Lynée and our collaborator Zhitao from @TantilloLab on the publication of a total synthesis of pupukeanane natural products in ACIE!
onlinelibrary.wiley.com/doi/…
